SOLVOLYTIC HYDROPEROXIDE REARRANGEMENTS IV. Selective Rearrangement of Spirooctan-4-ol.

DOI: 10.1016/S0040-4039(00)95667-3

Source and publish data:

Tetrahedron Letters p. 131 - 134 (1987)

Update date:2022-08-02

Topics:

Authors:

Ronald, Robert C.

Ruder, Suzanne M.

Lillie, Thomas S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95667-3

Rearrangement of spiro<5,2>octan-4-ol, 1, in acidified THF-H2O2 is a selective process in which substitution occurs with retention of configuration and ring-expansion with inversion of the carbinyl center.

Full text of DOI:10.1016/S0040-4039(00)95667-3

Products guided by the article

Product name:1-Oxaspiro[2.5]octan-4-ol

Cas No:794513-27-2

R&D Labs maybe for 794513-27-2

Suzhou CarbonWell Pharma-Tech Co., Ltd

Contact:Tel: + 86 (0)512-8898-1216; + 86-18606258602

Address:2358 Changan Road, Wujiang Scientific Innovation Park, Wujiang, Jiangsu Province, P. R. China 215200
Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
Improve Medical Technology(Nanxiong) Co., Ltd

Contact:86-751-3836997

Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Zhengzhou Institute of Chiral Pharmer Research Co., Ltd.

Contact:86-371-55219111

Address:15 Floor, 2 Building, Central China Technovalley, Zhongyuan West Road

Relevant to this article

β-Lactams. IX. The synthesis of 7-β-phenylacetamido-3'-hydroxybenzo-[3,4]-O-2-isocephem, a weak antibacterial β-lactam antibiotic

Doi:10.1139/v81-432
(1981)
Design and synthesis of calindol derivatives as potent and selective calcium sensing receptor agonists

Doi:10.1016/j.bmc.2015.12.019
(2016)
Synthesis, antimicrobial activity and molecular modeling studies of halogenated 4-[1H-imidazol-1-yl(phenyl)methyl]-1,5-diphenyl-1H-pyrazoles

Doi:10.1016/j.bmc.2004.07.029
(2004)
Pyrrole Studies. Part 26. A Novel Thermochromic and Photochromic Pyrrole System

Doi:10.1039/P19810002656
(1981)
Synthesis of Urazoles via Cycloaddition Employing 4-Phenyl-4H-1,2,4-Triazole-3,5-dione (PTAD) Transfer

Doi:10.1055/s-1986-31804
(1986)
The Photochemical Formation of Dihydrocarbazoles from Diphenylamines and Their Thermal Rearrangement and Disproportionation Reactions

Doi:10.1021/ja00413a019
(1981)

Article Doi