SOLVOLYTIC HYDROPEROXIDE REARRANGEMENTS IV. Selective Rearrangement of Spirooctan-4-ol.

DOI: 10.1016/S0040-4039(00)95667-3

Source and publish data:

Tetrahedron Letters p. 131 - 134 (1987)

Update date:2022-08-02

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Authors:

Ronald, Robert C.

Ruder, Suzanne M.

Lillie, Thomas S.

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Article abstract of DOI:10.1016/S0040-4039(00)95667-3

Rearrangement of spiro<5,2>octan-4-ol, 1, in acidified THF-H2O2 is a selective process in which substitution occurs with retention of configuration and ring-expansion with inversion of the carbinyl center.

Full text of DOI:10.1016/S0040-4039(00)95667-3

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