Journal of the Chemical Society, Dalton Transactions p. 2132 - 2136 (1981)
Update date:2022-08-02
Topics:
Cross, Ronald J.
Phillips, Ian G.
The addition of PMe2Ph to a single platinum atom of the dimer, instead of the more common symmetrical attack.Less ionic product is produced from the addition of PBu3 to a profound effect on the course of the reactions.The ionic materials are able to undergo rapid phosphine exchange even at -60 deg C if excess ligand (PR3 or Cl-) is present.These exchange reactions can complicate the range of products observed unless precautions are taken to prevent local accumulations of the phosphine in the course of mixing the reactants.
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Doi:10.1021/jo040296h
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(1981)
