Journal of the Chemical Society. Perkin transactions I p. 1501 - 1509 (1981)
Update date:2022-08-04
Topics:
Barrett, Anthony G. M.
Godfrey, Christopher R. A.
Hollinshead, David M.
Prokopiou, Panayiotis A.
Barton, Derek H. R.
et al.
Divers carboxylic esters have been reduced with dissolving Group 1A metals.Using lithium in ethylamine, sterically hindered esters (RCO2R') were deoxygenated giving the alkane (R'H) whereas non-hindered esters regenerated the parent alcohol (R'OH).This permitted the selective deoxygenation of diesters.Conversely, potassium-sodium eutectic solubilised with 18-crown-6 in t-butylamine and tetrahydrofuran (THF) efficiently deoxygenated both hindered and non-hindered esters.In the absence of nucleophiles at ambient temperture the principal reaction of carboxylic ester radical anions was deoxygenation.
View MoreShaanxi HuaTai Bio-fine chemical company Ltd
Contact:86-029-87862197
Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Henan Sinotech Import&Export Corporation
website:http://www.hasinotech.com
Contact:86-371-86181678
Address:No. 260, Dongming Road,Jinshui District
Zhejiang Quzhou Jiancheng Silicone Co., Ltd.(Shanghai Jiancheng Industial and Trade Co, Ltd)
Contact:18957018777 +86-570-3888777
Address:The company production base address： Quzhou City, Zhejiang Province high-tech industrial park Nianhua Road 37
Xinchang Yueding Chemical Co., Ltd.
Contact:86-571-56926323
Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Shanghai better-in Medical Technology Co.,LTD.
Contact:+86-21-38921049
Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Doi:10.1039/P19810002065
(1981)Doi:10.1016/j.bmcl.2006.09.050
(2007)Doi:10.1246/cl.1981.1439
(1981)Doi:10.1021/jo049121y
(2004)Doi:10.3390/molecules24142597
(2019)Doi:10.1021/jm00344a010
(1982)
