O-SILYLATED DIENOLATES IN ORGANIC SYNTHESIS: γ-SELECTIVE ALKYLATION OF UNSATURATED CARBONYL COMPOUNDS BY 1,3-DITHIENIUM FLUOROBORATE

DOI: 10.1016/S0040-4039(01)90565-9

Source and publish data:

Tetrahedron Letters p. 2833 - 2836 (1981)

Update date:2022-08-04

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Authors:

Paterson, Ian

Price, Lee G.

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Article abstract of DOI:10.1016/S0040-4039(01)90565-9

The alkylation of O-silylated dienolates of unsaturated aldehydes, ketones, and esters with 1,3-dithienium fluoroborate shows useful γ-selectivity.The γ-products are selectively protected 1,5-dicarbonyl compounds.

Full text of DOI:10.1016/S0040-4039(01)90565-9

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