
Journal of the Chemical Society, Dalton Transactions p. 1898 - 1905 (1981)
Update date:2022-08-04
Topics:
Middleton, A. Robert
Wilkinson, Geoffrey
The interaction of nitric oxide with peralkyl compounds of Zn, Cu, Re, Cr, Mo, W, and Zr and with the phosphine complexes Ni(ν-C5H5)Me(PPh3), CoMe3(PMe3)3, RhMe(PPh3)3 has been studied.In addition to N-alkyl-N-nitrosohydroxylaminate, ON(R)NO, complexes normally formed from diamagnetic alkyls, and η2 or bridged nitrosoalkane, ONR, compounds usually obtained from paramagnetic alkyls, complexes with M=O or M-O-M groups may be formed from the latter or from the interaction of NO with certain diamagnetic complexes that may give paramagnetic intermediates, e.g. by dissociation.Among new compounds characterised by i.r. and n.m.r. spectra are the tetrameric
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Doi:10.1248/cpb.29.2460
(1981)Doi:10.1016/0040-4039(64)83133-6
(1964)Doi:10.1139/cjc-2017-0328
(2017)Doi:10.1039/b405586c
(2004)Doi:10.1021/acs.analchem.1c01531
(2021)Doi:10.1021/jo00132a006
(1982)