Further Studies on the Interaction of Nitric Oxide with Transition-metal Alkyls

DOI: 10.1039/DT9810001898

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1898 - 1905 (1981)

Update date:2022-08-04

Topics:

Authors:

Middleton, A. Robert

Wilkinson, Geoffrey

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9810001898

The interaction of nitric oxide with peralkyl compounds of Zn, Cu, Re, Cr, Mo, W, and Zr and with the phosphine complexes Ni(ν-C5H5)Me(PPh3), CoMe3(PMe3)3, RhMe(PPh3)3 has been studied.In addition to N-alkyl-N-nitrosohydroxylaminate, ON(R)NO, complexes normally formed from diamagnetic alkyls, and η² or bridged nitrosoalkane, ONR, compounds usually obtained from paramagnetic alkyls, complexes with M=O or M-O-M groups may be formed from the latter or from the interaction of NO with certain diamagnetic complexes that may give paramagnetic intermediates, e.g. by dissociation.Among new compounds characterised by i.r. and n.m.r. spectra are the tetrameric >4, the nitric oxide adduct of hexamethylrhenium, ReMe6(NO), the complex Re2O3Me4(ONMe)2, and the oxo-compounds of molybdenum and tungsten of stoicheiometry M2O3(NO)2(ONR)2, R=CH2SiMe3 or CH2CMe3.The interaction of molybdenum and tungsten hexacarbonyl with nitrobenzene and nitromethane gives oxo-species with ONR groups.

Full text of DOI:10.1039/DT9810001898

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:trinitrosyltrioxohexakis(trimethylsilylmethyl)(triphenylphosphine)-triangulo-trirhenium

Cas No:79829-62-2

R&D Labs maybe for 79829-62-2

Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Jinan Jianfeng Chemical Co., Ltd

Contact:0086-531-88110457

Address:sales01(-a-t-)pharmachemm{dot}c+o+m
Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai

Relevant to this article

Studies on 3,5-dioxopiperidines and related compounds. Synthesis of 5-(3-tert-butylamino-2-hydroxy)propoxy-1,2,3,4-tetrahydro-2-oxo-1,7-naphthyr idine

Doi:10.1248/cpb.29.2460
(1981)
Doi:10.1016/0040-4039(64)83133-6
(1964)
Efficient and selective iron-mediated reductive Claisen rearrangement of propargyloxyanthraquinones to anthrafurandiones in ionic liquids

Doi:10.1139/cjc-2017-0328
(2017)
Palladium(II) complexes of new OPN phosphine ligands and their application in homogeneously catalysed reactions of CO with alkenes or alkynes

Doi:10.1039/b405586c
(2004)
Rare Self-Luminous Mixed-Valence Eu-MOF with a Self-Enhanced Characteristic as a Near-Infrared Fluorescent ECL Probe for Nondestructive Immunodetection

Doi:10.1021/acs.analchem.1c01531
(2021)
Rearrangements in the Halogenation of Tetraalkylethylenes with N-Halosuccinimides and tert-Butyl Hypochlorite

Doi:10.1021/jo00132a006
(1982)

Article Doi