CATIONIC CYCLIZATION OF GERANONITRILE AND RELATED COMPOUNDS VIA THEIR BROMOHYDRINS: APPLICATION TO THE SYNTHESIS OF (+/-)-SNYDEROLS

DOI: 10.1246/cl.1981.1125

Source and publish data:

Chemistry Letters p. 1125 - 1128 (1981)

Update date:2022-08-04

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Authors:

Murai, Akio

Abiko, Atsushi

Kato, Koji

Masamune, Tadashi

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Article abstract of DOI:10.1246/cl.1981.1125

Cationic cyclization of bromohydrins of geranonitrile and homogeranonitrile in the presence of boron trifluoride complexes proceeded smoothly, giving mixtures of bromo cyclic olefins in satisfactory yields.This cyclization method was applied to the synthesis of (+/-)-snyderols.

Full text of DOI:10.1246/cl.1981.1125

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