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Charge-transfer Luminescence from Mixed-ligand, 2,2',2''-Terpyridine-Phosphine, Complexes of Osmium(II)

DOI: 10.1039/c39810000793

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 793 - 795 (1981)

Update date:2022-07-30

Topics:

Authors:

Allen, George H.Allen, George H.

Sullivan, B. PatrickSullivan, B. Patrick

Meyer, Thomas J.Meyer, Thomas J.

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Article abstract of DOI:10.1039/c39810000793

The first example of intense room temperature charge-transfer (CT) emission from a series of metal-terpyridine complexes <II(trpy)(diphosph)L>n+ (trpy = 2,2',2''-terpyridine and diphosph is, e.g., Ph2PCH2PPh2)> in fluid solution is reported; the complexes can have relatively long CT excited-state lifetimes while also exhibiting substitutional photochemistry.

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Product name:[Os(II)(trpy)(dppm)Cl](1+)

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