TRANSITION METAL-CATALYZED SYNTHESES OF ORGANIC ACIDS BY CHELATION-PROMOTED REGIOSELECTIVE DOUBLE BOND INSERTION

DOI: 10.1016/0022-328X(81)85022-X

Source and publish data:

Journal of Organometallic Chemistry p. C16 - C20 (1981)

Update date:2022-07-30

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Authors:

Chiusoli, G. Paolo

Salerno, Giuseppe

Giroldini, William

Pallini, Luciano

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Article abstract of DOI:10.1016/0022-328X(81)85022-X

The rhodium- or nickel-catalyzed reaction of vinylic halides with alkali salts of 3-butenoic acids leads to regioselective formation of dienoic acids, containing 3,5-conjugated double bonds.Monoarylacetylenes also react with 3-butenoic acids in a rhodium-

Full text of DOI:10.1016/0022-328X(81)85022-X

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