Bulletin of the Chemical Society of Japan p. 2672 - 2674 (1981)
Update date:2022-09-26
Topics:
Kajimoto, Tsunesuke
Kitano, Yukishige
Takahashi, Hidetaka
Tsuji, Jiro
Bis(cyclohexyl isocyanide)palladium(II) chloride, PdCl2(C6H11NC)2 (1) was prepared from PdCl2.The configuration of the complex 1 is cis with respect to the isocyanides.The isocyano group in one cyclohexyl isocyanide takes axial conformation to chair form cyclohexyl group, while another takes equatorial conformation.By recrystallization of 1 from benzene bis(cyclohexyl isocyanide)palladium(II) chloride-benzene, PdCl2(C6H11NC)2(C6H6)2 (2) was prepared.IR spectrum of 2 shows a characteristics absorption at 700 cm-1 which is due to the benzene incorporated in the complex.Similar benzene complex was also prepared from PdBr2.
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(1981)Doi:10.1016/S0040-4039(00)98475-2
(1985)Doi:10.1016/j.bmcl.2006.12.019
(2007)Doi:10.1016/j.jfluchem.2003.11.034
(2004)Doi:10.1016/0040-4039(96)00678-8
(1996)Doi:10.1021/ja00372a027
(1982)
