The Formylation of an Aromatic Nucleus by the Use of 2-Ethoxy-1,3-dithiolane

DOI: 10.1246/bcsj.54.2120

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2120 - 2123 (1981)

Update date:2022-08-05

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Authors:

Jo, Shigeo

Tanimoto, Shigeo

Sugimoto, Toyonari

Okano, Masaya

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Article abstract of DOI:10.1246/bcsj.54.2120

The reaction of various phenols with 2-ethoxy-1,3-dithiolane proceeded smoothly in the presence of BF3*Et2O to afford 1,3-dithiolan-2-ylated phenols, which were readily hydrolyzed to the corresponding aldehydes.This process was also extended to N,N-dimethylaniline and indole.

Full text of DOI:10.1246/bcsj.54.2120

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