THE REACTION OF H2PtCl6 WITH AROMATIC COMPOUNDS IN CF3COOH/H2O AFFORDING THE ANIONIC ?-ARYL COMPLEXES OF PLATINIUM(IV). IV. THE SYNTHESIS OF PLATINUM(IV) COMPLEXES OF FLUORINATED BENZENES AND THE ELECTRONIC INFLUENCE OF THE PLATINUM MOIETY

Article abstract of DOI:10.1016/S0022-328X(00)81924-5

The reaction of H2PtCl6 with fluorobenzene, o-chlorofluorobenzene and m-chlorofluorobenzene in CF3COOH/H2O affords anionic ?-aryl complexes of platinum(IV).The first two compounds give rise to mixtures of two isomers (meta and para), the latter forms only