New Synthesis of Spiro Phosphorane by Using Diphenyl Disulfide. A Facile Route to Cyclic Acyloxyphosphoranes from α-Hydroxy Acids

DOI: 10.1021/jo00345a003

Source and publish data:

Journal of Organic Chemistry p. 916 - 919 (1982)

Update date:2022-07-29

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Authors:

Kimura, Yoshiharu

Miyamoto, Masatoshi

Saegusa, Takeo

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Article abstract of DOI:10.1021/jo00345a003

Five-membered 1,3,2-dioxaphospholanes were subjected to reaction with 1,2- and 1,3-glycols, with 2-(methylamino)ethanol, and with α-hydroxy acids in the presence of diphenyl disulfide to produce various derivatives of spiro oxyphosphoranes 3 and 5.The rea

Full text of DOI:10.1021/jo00345a003

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