Reactivity of cis-Bis(dimethylphenylsilyl)bis(phosphine)platinum Complexes toward Unsaturated Compounds Relevant to Double Silylation

DOI: 10.1246/cl.1989.467

Source and publish data:

Chemistry Letters p. 467 - 470 (1989)

Update date:2022-07-29

Topics:

Authors:

Kobayashi, Toshi-aki

Hayashi, Teruyuki

Yamashita, Hiroshi

Tanaka, Masato

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1989.467

The reaction of phenylacetylene, tolane, or isoprene with cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum readily took place to result in 1,2- or 1,4- double silylation, respectively.Ethylene also underwent double silylation with the platinum complex, but styrene selectively gave E-2-(dimethylphenylsilyl)styrene.

Full text of DOI:10.1246/cl.1989.467

Products guided by the article

Product name:Silane, (2-methyl-2-butene-1,4-diyl)bis[dimethylphenyl-, (E)-

Cas No:84812-54-4

R&D Labs maybe for 84812-54-4

Beijing Pure Chem Co.,Ltd.

Contact:+86-10-83993285

Address:Rm.1708, Haobai Tower, Building 6, No.50, North Road, West Third Ring, Haidian District, Beijing, China
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Xinchang Jiu Xin Pharmaceutical Co., Ltd

website:http://www.jiuxinpharm.com

Contact:86 137 5756 8585

Address:Poyang industry Park
Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China

Relevant to this article

Herstellung und Solvolyse von 3-substituierten p-Toluolsulfonsaeure-(1-adamantyl)estern

Doi:10.1002/hlca.19820650607
(1982)
Preparation and properties of oligocytidylates with 2'-5' internucleotide linkage

Doi:10.1246/bcsj.58.361
(1985)
α:β Selectivity in the synthesis of 3-substituted, 4-methyl umbelliferone glycosides of N-acetyl glucosamine and chitobiose

Doi:10.1016/j.tetasy.2004.11.053
(2005)
Cyanoacetanilides intermediates in heterocyclic synthesis. Part 1: A facile synthesis of polysubstituted and condensed pyridones

Doi:10.1002/jccs.200400145
(2004)
Palladium-catalysed C-C coupling reactions in the enantioselective synthesis of 2,4-disubstituted 4,5-dehydropiperidines using galactosylamine as a stereodifferentiating auxiliary

Doi:10.1016/j.tetasy.2004.11.074
(2005)
Benzocycloheptynedicobalt complexes by intramolecular Nicholas reactions

Doi:10.1055/s-2004-837215
(2005)

Article Doi