Chemistry Letters p. 467 - 470 (1989)
Update date:2022-07-29
Topics:
Kobayashi, Toshi-aki
Hayashi, Teruyuki
Yamashita, Hiroshi
Tanaka, Masato
The reaction of phenylacetylene, tolane, or isoprene with cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum readily took place to result in 1,2- or 1,4- double silylation, respectively.Ethylene also underwent double silylation with the platinum complex, but styrene selectively gave E-2-(dimethylphenylsilyl)styrene.
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