Reactivity of cis-Bis(dimethylphenylsilyl)bis(phosphine)platinum Complexes toward Unsaturated Compounds Relevant to Double Silylation

DOI: 10.1246/cl.1989.467

Source and publish data:

Chemistry Letters p. 467 - 470 (1989)

Update date:2022-07-29

Topics:

Authors:

Kobayashi, Toshi-aki

Hayashi, Teruyuki

Yamashita, Hiroshi

Tanaka, Masato

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1989.467

The reaction of phenylacetylene, tolane, or isoprene with cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum readily took place to result in 1,2- or 1,4- double silylation, respectively.Ethylene also underwent double silylation with the platinum complex, but styrene selectively gave E-2-(dimethylphenylsilyl)styrene.

Full text of DOI:10.1246/cl.1989.467

Products guided by the article

Product name:Silane, (2-methyl-2-butene-1,4-diyl)bis[dimethylphenyl-, (E)-

Cas No:84812-54-4

R&D Labs maybe for 84812-54-4

Henan zhongda Biological Engineering Co., Ltd

Contact:86-28-18109029985

Address:shenzhou road,xuedian industrial estate,zhengzhou city,henan province CHN
QUZHOU ZIO I/E CO.;LTD

Contact:13357117572

Address:No.149 Shiji dadao Road.
Changyi Xinxing Technology Development Co., Ltd.

Contact:0086-510-86651065(Time Zone:8),86651656

Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China
Changde Yungang Biotechnology Co., Ltd

website:http://www.cdyg.com

Contact:+86-736-7391178

Address:Qiaonan Industrial Park, Changde City, Hunan Province
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China

Relevant to this article

Herstellung und Solvolyse von 3-substituierten p-Toluolsulfonsaeure-(1-adamantyl)estern

Doi:10.1002/hlca.19820650607
(1982)
Preparation and properties of oligocytidylates with 2'-5' internucleotide linkage

Doi:10.1246/bcsj.58.361
(1985)
α:β Selectivity in the synthesis of 3-substituted, 4-methyl umbelliferone glycosides of N-acetyl glucosamine and chitobiose

Doi:10.1016/j.tetasy.2004.11.053
(2005)
Cyanoacetanilides intermediates in heterocyclic synthesis. Part 1: A facile synthesis of polysubstituted and condensed pyridones

Doi:10.1002/jccs.200400145
(2004)
Palladium-catalysed C-C coupling reactions in the enantioselective synthesis of 2,4-disubstituted 4,5-dehydropiperidines using galactosylamine as a stereodifferentiating auxiliary

Doi:10.1016/j.tetasy.2004.11.074
(2005)
Benzocycloheptynedicobalt complexes by intramolecular Nicholas reactions

Doi:10.1055/s-2004-837215
(2005)

Article Doi