Reactivity of cis-Bis(dimethylphenylsilyl)bis(phosphine)platinum Complexes toward Unsaturated Compounds Relevant to Double Silylation

DOI: 10.1246/cl.1989.467

Source and publish data:

Chemistry Letters p. 467 - 470 (1989)

Update date:2022-07-29

Topics:

Authors:

Kobayashi, Toshi-aki

Hayashi, Teruyuki

Yamashita, Hiroshi

Tanaka, Masato

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Article abstract of DOI:10.1246/cl.1989.467

The reaction of phenylacetylene, tolane, or isoprene with cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum readily took place to result in 1,2- or 1,4- double silylation, respectively.Ethylene also underwent double silylation with the platinum complex, but styrene selectively gave E-2-(dimethylphenylsilyl)styrene.

Full text of DOI:10.1246/cl.1989.467

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