Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 3. Synthesis of (-)-Frontalin

DOI: 10.1021/jo00345a007

Source and publish data:

Journal of Organic Chemistry p. 935 - 940 (1982)

Update date:2022-09-26

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Authors:

Jarosz, Slawomir

Hicks, David R.

Fraser-Reid, Bert

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Article abstract of DOI:10.1021/jo00345a007

3-Deoxy-2-oxo glycosides with and without a C4 hydroxyl group are readily prepared from methyl α-D-glucopyranoside.Reaction with methylmagnesium iodide gives the C2 tertiary alcohol with an axially oriented methyl group.The epimeric tertiary alcohol can b

Full text of DOI:10.1021/jo00345a007

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