Tetrahedron Letters p. 1813 - 1816 (1987)
Update date:2022-08-04
Topics:
Pradhan, Suresh K.
Thakker, Krishanlal R.
McPhail, Andrew T.
Total enantioselectivity has been observed in pinacol formation using Li/THF. (+) Camphor and (+/-) Camphor give the optically active and racemic form of a single pinacol whose stereochemistry has been established as endo:endo by X-ray analysis.An exo:endo pinacol is formed as the sole product if camphor is added to Li/NH3.Tentative mechanism is proposed.
View MoreDaqing New Century Fine Chemical Co., Ltd.(expird)
Contact:010-57126694
Address:No.39, jinxing cun, honggang district
SINO Industries Company Limited(expird)
Contact:86-29-85369724
Address:No.111, Jiefang Road, Xi’an, China
Liaoning Yufeng Chemical Co.,Ltd.
Contact:86-0419-3418888
Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Contact:+86-21-61318535
Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
QINGDAO HONG JIN CHEMICAL CO.,LTD.
website:http://www.hongjinchem.com
Contact:+86-532-83657313
Address:2ND Building, 8 Shangqing Road, Qingdao, Shandong Province, China.
Doi:10.1039/d1sc01028j
(2021)Doi:10.1246/bcsj.54.3869
(1981)Doi:10.1021/jo00132a004
(1982)Doi:10.1016/S0008-6215(00)80791-0
(1982)Doi:10.1081/SCC-200034770
(2004)Doi:10.1038/s41429-019-0199-3
(2019)
