STEREOSELETIVITIES IN THE REACTIONS OF α-D-HEXOPYRANOSID-4-ULOSES WITH DIAZOMETHANE

DOI: 10.1016/S0008-6215(00)80685-0

Source and publish data:

Carbohydrate Research p. 221 - 238 (1982)

Update date:2022-09-26

Topics: NMR spectroscopy Reactions Organic synthesis Diazomethane Reaction Conditions Gas Chromatography Stereoisomer

Authors:

Sato, Ken-Ichi

Yoshimura, Juji

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Article abstract of DOI:10.1016/S0008-6215(00)80685-0

The stetreoselectivities in the reactions of diazomethane with various α-D-hexopyranosid-4-uloses are compared with those in Grignard reactions.The results support the hypothesis that the stereoselectivity of the diazomethane reaction is mainly controlled

Full text of DOI:10.1016/S0008-6215(00)80685-0

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