Journal of Organometallic Chemistry p. 1 - 10 (1981)
Update date:2022-08-04
Topics:
Mikhailov, B. M.
Shagova, E. A.
Etinger, M. Yu.
1-Boraadamantane (I) reacts with Et2NCl, NH2OSO3H or 2,4-(NO2)2C6H3ONH2 to form the 7-diethylaminomethyl- or 7-aminomethyl derivatives of 3-borabicyclo<3.3.1>nonane containing Cl, SO3H or 2,4-(NO2)2C6H3O groups at the 3 position.Oxidation of the 7-aminomethyl derivative affords cis-1,3-di(hydroxymethyl)-5-aminomethylcyclohexane.I reacts with AlkNCl2 to form N-alkyl-3-azabicyclo<3.3.1>nonanes with the dichloroborylmethyl fragment at the 7 position.Oxidation of the latter compounds gave 3-alkyl-7-hydroxymethyl-3-azabicyclo<3.3.1>nonanes.
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(1981)
