Thermal Rearrangements of 2-Cyclopropylcycloalk-2-enones

DOI: 10.1039/P19810003147

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3147 - 3149 (1981)

Update date:2022-08-03

Topics:

Authors:

Pattenden, Gerald

Whybrow, Derek

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19810003147

Thermolysis of 2-(2,2-dimethylcyclopropyl)cyclopent-2-enone (2) and 2-cyclopropylcyclohex-2-enone (6) is shown to produce 2-(3-methylbut-2-enylidene)cyclopentanone (10) and 2-propylphenol (14), respectively, via homo<1,5>sigmatropic H-migration and isomerisation.Heating 2-cyclopropylcyclopent-2-enone (8) under a variety of conditions led only to decomposition; no products resulting from vinylcyclopropane - cyclopentene rearrangement were detected.

Full text of DOI:10.1039/P19810003147

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-cyclopropyl-2-isobutoxycyclohex-2-enol

Cas No:81071-58-1

R&D Labs maybe for 81071-58-1

ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Beijing Top Science biological technology co., LTD

Contact:+86-13439059536

Address:15-1705 jre three mile, Beijing 100000,CHINA
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP

Relevant to this article

Nucleotide Analog ARL67156 as a Lead Structure for the Development of CD39 and Dual CD39/CD73 Ectonucleotidase Inhibitors

Doi:10.3389/fphar.2020.01294
(2020)
1-(3-dimethylamino-1-phenylpropyl)piperazines and related compounds: Synthesis and pharmacological screening

Doi:10.1135/cccc19812729
(1981)
Novel Synthesis of Pyrazolo<5,1-c>-1,2,4-Triazoles, Imidazo<1,2-b>pyrazoles, and <1,2,4>-Triazolo<4,3-a>benzimidazoles. Reaction of Nitrile Imines with Amino- and Oxo-substituted Diazoles

Doi:10.1039/P19820002663
(1982)
On the rapid synthesis of highly substituted proline analogues by 5-endo-trig iodocyclisation

Doi:10.1016/j.tetlet.2006.02.017
(2006)
Doi:10.1021/ja00803a020
(1973)
An improved synthesis of 5,7-dimethoxy-4-methyl-phthalide, a key intermediate in the synthesis of mycophenolic acid

Doi:10.1080/00397919608003548
(1996)

Article Doi