Reactions between Enaminones and Enones. Part 2. C versus N-Alkylation with Cyclohex-2-enone. Structure Confirmation by Reduction of a Dienaminone Derivative of Dehydrated Dimedone Dimer

DOI: 10.1039/P19810003120

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3120 - 3124 (1981)

Update date:2022-08-03

Topics: Reduction Structure Confirmation Enaminones Enones

Authors:

Chaaban, Ibrahim

Greenhill, John V.

Ramli, Mohamed

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Article abstract of DOI:10.1039/P19810003120

Primary and secondary enaminones derived from cyclohexane-1,3-dione, dimedone, and acetylacetone react with cyclohexenone to give exclusively C-alkylated derivatives.In every case the products form carbinolamines which exist as 1-hydroxy-2-azacyclo<3.3.1>

Full text of DOI:10.1039/P19810003120

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