Photolysis of Organopolysilanes. Photochemical Behavior of Phenylethynyldisilanes

DOI: 10.1021/ja00374a029

Source and publish data:

Journal of the American Chemical Society p. 2872 - 2878 (1982)

Update date:2022-08-05

Topics: Radical reactions Polymerization

Authors:

Ishikawa, Mitsuo

Sugisawa, Hiroshi

Fuchikami, Takamasa

Kumada, Makoto

Yamabe, Tokio

et al. et al.

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Article abstract of DOI:10.1021/ja00374a029

The photolysis of phenylethynylpentamethyldisilane (1) afforded 1,1-dimethyl-2-phenyl-3-trimethylsilyl-1-silacyclopropene (8) and 1,1-dimethyl-3-phenyl-3-trimethylsilyl-1-silapropadiene.The absorption and emission spectra of 1 were measured at 300 and 77

Full text of DOI:10.1021/ja00374a029

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