Journal of the Chemical Society. Perkin transactions II p. 1599 - 1605 (1981)
Update date:2022-08-03
Topics:
Ohmori, Hidenobu
Ueda, Chihiro
Nobusue, Yasuhiro
Saitou, Naoko
Yokota, Tomoko
Masui, Masaichiro
Anodic oxidation in methanol of N-methylcarbanilides with an alkoxy-group para to the nitrogen atom (I) gives the intramolecular cyclization products, N-methylbenzoxazolium perchlorates: no cyclization product is obtained in the electrolysis of the anilides in acetonitrile.The process of cyclization was investigated by cyclic voltammetry, controlled potential electrolysis, and open circuit relaxation experiments using an optically transparent glassy carbon electrode.In spectroelectrochemical experiments on 4'-methoxy-N-methylbenzanilides (Ib-d) in methanol, accumulation of a metastable intermediate has been demonstrated.A possible reaction sequence for the formation of the benzoxazolium salts is discussed.
View MoreChangsha Nutritopper Bio Technology Co.,Ltd.
Contact:+86-731-87803543
Address:East 1st Street, Baima Road, Ningxiang County
Contact:+86-511-88790000
Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
Contact:86-571-86737118-8689
Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Changzhou Yongxu Chemical Co.,Ltd
Contact:86-0519-85286591
Address:Room 1812,Wanda Plaza B,Xinbei District,Changzhou,Jiangsu,China
Taizhou Elitechemie MediPharma Technology Co.,Ltd.
Contact:+86-523-86810021
Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Doi:10.1021/ja300092w
(2012)Doi:10.1021/jo00133a004
(1982)Doi:10.1016/S0022-328X(00)86823-0
(1982)Doi:10.1007/BF00814340
(1982)Doi:10.1016/S0040-4039(00)80062-3
(1988)Doi:10.1246/cl.1982.387
(1982)
