Pentamethylcyclopentadienyl-rhodium and -iridium Complexes. Part 31. Tri-μ-phenoxo-rhodium Complexes and a Facile H/D Exchange Reaction

DOI: 10.1039/DT9810002335

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2335 - 2338 (1981)

Update date:2022-09-26

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Authors:

Nutton, Andrew

Maitlis, Peter M.

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Article abstract of DOI:10.1039/DT9810002335

<2(OH)3> reacts with phenol to give <2(OPh)3> (3), containing three μ-phenoxo-ligands.The related complexes <2(OH)3>X (X=Cl or OH) react with phenol to give <n> which is formulated as the tri-μ-phenoxo-complex <2(OPh)3><(PhO)5H4> (4), largely on the basis of the 13C n.m.r. spectra.The methyl hydrogens in (4) exchange very rapidly for deuterium in <2H6>acetone solution.

Full text of DOI:10.1039/DT9810002335

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