Pentamethylcyclopentadienyl-rhodium and -iridium Complexes. Part 31. Tri-μ-phenoxo-rhodium Complexes and a Facile H/D Exchange Reaction

DOI: 10.1039/DT9810002335

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2335 - 2338 (1981)

Update date:2022-09-26

Topics:

Authors:

Nutton, Andrew

Maitlis, Peter M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9810002335

<2(OH)3> reacts with phenol to give <2(OPh)3> (3), containing three μ-phenoxo-ligands.The related complexes <2(OH)3>X (X=Cl or OH) react with phenol to give <n> which is formulated as the tri-μ-phenoxo-complex <2(OPh)3><(PhO)5H4> (4), largely on the basis of the 13C n.m.r. spectra.The methyl hydrogens in (4) exchange very rapidly for deuterium in <2H6>acetone solution.

Full text of DOI:10.1039/DT9810002335

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Rh₂(C₅(CH₃)5)2(OC₆H₅)3]⁽¹⁺⁾*[PF₆]^(1-)=[Rh₂(C₅(CH₃)5)2(OC₆H₅)3][PF₆]

Cas No:81241-31-8

R&D Labs maybe for 81241-31-8

Shanghai Run-Biotech Co., Ltd.

website:http://www.run-biotech.com

Contact:+86-21-31576854/57171705 / 57171706

Address:second floor, building 3, No.999, jiangyue Road, minghang District, Shanghai, China
Jiangsu Feymer Technology Co., Ltd.

Contact:+86-512-58110132

Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
shanghai hekang chemical co.ltd

Contact:021-54173790

Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China

Relevant to this article

Synthetic, structural, and mechanistic aspects of an amine activation process mediated at a zwitterionic Pd(II) center

Doi:10.1021/ja046415s
(2004)
Unequivocal determination of glucuronides, in particular of clofibric β-glucuronide

Doi:10.1002/ardp.19823150512
(1982)
Adamantane and its derivatives. 1. Hydrazones and pyrazolones of adamantane

Doi:10.1007/BF00503563
(1982)
Kinetic Resolution of Racemic α-Methylbenzyl Methacrylate: Asymmetric Selective Polymerization Catalyzed by Grignard Reagent-(-)-Sparteine Derivative

Doi:10.1021/ja00381a019
(1982)
Kinetics and Mechanism of the Conjugate Hydrocyanation of α,β-Unsaturated Ketones by the Potassium Cyanide-Ammonium Chloride System

Doi:10.1021/jo00139a041
(1982)
Planar dimeric six-membered spirane aluminum hydrazide: Synthesis and X-ray crystal structure of [LAlN(Me)NH]₂ (L = HC{(2,6-i-Pr ₂C₆H₃N)(CMe)}₂)

Doi:10.1021/om049560n
(2004)

Article Doi