
Journal of the Chemical Society. Chemical communications p. 508 - 510 (1992)
Update date:2022-08-03
Topics:
Sen, Ayusman
Lin, Minren
A combination of platinum(II) ion and metallic platinum is found to oxidise ethane to a mixture of acetic and glycolic acids in aqueous medium in the presence of oxygen; the platinum(II) ion is responsible for the initial C-H activation step leading eventually to the formation of ethanol and ethylene glycol, while metallic platinum catalyses the subsequent air oxidation of the alcohols to the corresponding acids.
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