Tetrahedron Letters p. 47 - 50 (1982)
Update date:2022-08-03
Topics:
Mattay, Jochen
Scharf, Hans-Dieter
1,3-Oxathioles 5 are formed in high yields upon treatment of 5-chloromethyl-1,3-oxathiolanes 3 with potassium t-butoxide in dimethyl sulfoxide at room temperature.The protoncatalyzed fragmentation of 5 leads in good yields to the new β-thia-γ,δ-enones 6.
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Doi:10.1055/s-0035-1561431
(2016)Doi:10.1016/S0008-6215(00)88056-8
(1982)Doi:10.1016/S0040-4020(01)93279-X
(1981)Doi:10.1002/ejoc.201001264
(2011)Doi:10.1021/jo00136a044
(1982)Doi:10.1021/ja00379a013
(1982)
