1,n-TRIORGANOSILYL MIGRATIONS IN THE REARRANGEMENTS OF SILYL-SUBSTITUTED ORGANOLITHIUM COMPOUNDS

DOI: 10.1016/S0022-328X(00)86806-0

Source and publish data:

Journal of Organometallic Chemistry p. 5 - 24 (1982)

Update date:2022-08-05

Topics: Rearrangements Organolithium compounds

Authors:

Eisch, John J.

Tsai, Miin-Rong

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Article abstract of DOI:10.1016/S0022-328X(00)86806-0

Under the agency of the potent lithiating agent, n-butyllithium in TMEDA, an array of organosilanes was found to undergo 1,n-silyl rearangements via carbanionic intermediates.Unambiguous 1,2-, 1,3- and 1,4-silyl shifts were unconvered in 1-trimethylsilyl-

Full text of DOI:10.1016/S0022-328X(00)86806-0

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