Journal of Organometallic Chemistry p. 5 - 24 (1982)
Update date:2022-08-05
Eisch, John J.
Tsai, Miin-Rong
Under the agency of the potent lithiating agent, n-butyllithium in TMEDA, an array of organosilanes was found to undergo 1,n-silyl rearangements via carbanionic intermediates.Unambiguous 1,2-, 1,3- and 1,4-silyl shifts were unconvered in 1-trimethylsilyl-
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