Tetrahedron Letters p. 1267 - 1270 (1982)
Update date:2022-08-02
Topics:
Nishiyama, Hisao
Yokoyama, Hiroshi
Narimatsu, Shinzo
Itoh, Kenji
The 1-trimethylsilylmethylvinyl group, as a 1-hydroxymethylvinyl equivalent, was readily introduced to epoxides with the corresponding Grignard reagent derived from 2-bromoallyltrimethylsilane.Obtained 2-(2-hydroxyethyl)-allylsilanes were converted to α-methylene-γ-lactones via diols.
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(2004)
