Reaction of 1,8-Bis(phenylethynyl)naphthalene with Phenylchlorocarbene: Formation of an Intermolecular Cyclization Product from Carbene Monoadduct and of 1,8-Naphthylenebis(diphenylcyclopropenylium) Dication from the Bisadduct

DOI: 10.1021/jo00387a013

Source and publish data:

Journal of Organic Chemistry p. 2183 - 2192 (1987)

Update date:2022-08-02

Topics:

Authors:

Komatsu, Koichi

Arai, Mikiro

Hattori, Yoshiyuki

Fukuyama, Keiichi

Katsube, Yukiteru

Okamoto, Kunio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00387a013

The reactions of 1,8-bis(phenylethynyl)naphthalene (4) with phenylchloro- and dichlorocarbenes and chemistry of the obtained products have been studied.The reaction of 4 with 1 equiv of phenylchlorocarbene exclusively affords spirocyclopropene 8, whose st

Full text of DOI:10.1021/jo00387a013

Products guided by the article

Product name:1-(3-chloro-2,3-diphenyl-1-cyclopropen-1-yl)-5-(phenylethynyl)naphthalene

Cas No:81701-37-3

R&D Labs maybe for 81701-37-3

FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD
Changsha Easchem Co.,Limited

website:http://www.easchem.com

Contact:+86-731-89722861 89722891

Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.
Shanghai Apeptide Co., Ltd.

website:http://www.apeptides.com/en/

Contact:+86-21-60871011

Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Chongqing Yawei Fine Chemical Co.,Ltd

Contact:0086-23-62849407

Address:Ziyou village, Nanquan town, Banan district, Chongqing China

Relevant to this article

Doi:10.1021/ja01860a005
(1940)
Michael addition reactions with η²-coordinaied anisoles: Controlling the stereochemistry of the para and benzylic carbons

Doi:10.1021/ja047054j
(2004)
Studies on the constituents of asclepiadaceae plants. LVIII. The structures of five glycosides, cynatratoside-A, -B, -C, -D, and -E, from the Chinese drug 'Pai-Wei', Cynanchum atratum BUNGE

Doi:10.1248/cpb.33.1507
(1985)
Micellar Dediazoniation: Dramatic Directive Effects on the Course of Reaction

Doi:10.1021/ja00383a008
(1982)
Reaction of 3-Nitroso-2-phenylimidazo<1,2-a>pyridine with Triethyl Phosphite. A Revised Structure for the Product

Doi:10.1021/jo00139a034
(1982)
Sulfur, tin and gold derivatives of 1-(2′-pyridyl)-ortho-carborane, 1-R-2-X-1,2-C₂B₁₀H₁₀ (R = 2′-pyridyl, X = SH, SnMe₃ or AuPPh₃)

Doi:10.1039/B411099D
(2004)

Article Doi