SYNTHESIS APPLICATIONS OF AZA-COPE REARRANGEMENTS; A STEREOSELECTIVE SYNTHESIS OF 9a-ARYLHYDROLILOLIDINES ALKALOIDS

DOI: 10.1016/S0040-4020(01)93279-X

Source and publish data:

Tetrahedron p. 4041 - 4045 (1981)

Update date:2022-08-03

Topics:

Authors:

Overman, Larry E.

Sworin, Michael

Bass, Lawrence S.

Clardy, Jon

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Article abstract of DOI:10.1016/S0040-4020(01)93279-X

A "Mannic-directed" 2-azonia-<3,3>-sigmatropic rearrangement is the key step in a new, completely stereoselective, method for preparing 9a-arylhydrolilolidines.Specifically, cis-fused bicyclic aminoalcohols 24 upon treatment with formaldehyde and acid aff

Full text of DOI:10.1016/S0040-4020(01)93279-X

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