
Journal of the Chemical Society. Chemical communications p. 845 - 847 (1982)
Update date:2022-08-03
Topics:
Koreeda, Masato
Tanaka, Yoshio
The reaction of in situ generated γ-alkoxyallylaluminium compounds with aldehydes or ketones at -78 deg C leads to the highly diastereoselective formation of mono-protected vicinal diols; the precursor to exo-brevicomin was efficiently synthesised using t
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