Journal of Organic Chemistry p. 3679 - 3684 (1982)
Update date:2022-08-03
Topics:
Zefirov, N.S.
Koz'min, A.S.
Zhdankin, V.V.
Nikulin, A.V.
Zyk, N.V.
The reaction of a series of olefins with chlorine and bromine in the presence of a large excess of lithium perchlorate in ether gave 1,2-halo perchlorates together with the corresponding 1,2-dihalides.Analogous reactions of NO2BF4 in methylene chloride or ethyl acetate with monoolefins gave 1,2-nitro perchlorates.Norbornadiene reacted with a NO2BF4/LiClO4 system to give two isomeric nitro perchlorates of nortricyclenic structure.Several synthetic and mechanistic aspects of this new reaction of electrophilic perchloration of olefins are discussed.
View MoreXi'an Unique Electronic and Chemical Co., Ltd.
Contact:+86-029-88238008
Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Shanghai Dano Pharmaceutical Co.,Ld.(expird)
Contact:+86-592-6266840
Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
Jiangsu Fengshan Group Co., Ltd.
Contact:86-25-86558671
Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China
WEIFANG DERUN CHEMICAL CO.,LTD
Contact:86-536-8956886
Address:weifang
Arshine Pharmaceutical Co., Limited
website:http://www.cnarshine.com
Contact:0731-88503671
Address:Room 1109.Block C3, Lugu Enterprise Plaza,No.27 Wenxuan Road,Changsha National Hi-Tech Industrial Development Zone,Hunan ,P.R.China
Doi:10.1021/jm00170a018
(1990)Doi:10.1016/0006-3002(53)90085-7
(1953)Doi:10.1002/ejoc.200400756
(2005)Doi:10.1248/cpb.30.1352
(1982)Doi:10.1021/ja00381a046
(1982)Doi:10.1021/ja01649a057
(1954)