Kinetic Applications of Electron Paramagnetic Resonance Spectroscopy. 38. Rearrangement of β-(Acyloxy)alkyl and β-(benzoyloxy)alkyl Radicals

DOI: 10.1021/ja00380a014

Source and publish data:

Journal of the American Chemical Society p. 4399 - 4403 (1982)

Update date:2022-08-03

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Authors:

Barclay, L. R. C.

Griller, D.

Ingold, K. U.

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Article abstract of DOI:10.1021/ja00380a014

Rate constants for the free-radical rearrangement, RC(O)OCMe2CH2* --> RC(O)OCH2CMe2*, and for the ring-opening reaction, , have been measured by kinetic EPR spectroscopy.In hydrocarbon solvents at 75 deg C with R = methyl and phenyl, the 1,2-acy

Full text of DOI:10.1021/ja00380a014

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