BREAKDOWN OF CYCLIC DITHIOHEMIORTHOAMIDE TETRAHEDRAL INTERMEDIATES - RC(SR')(NR2'')SH - AT SUB-ZERO TEMPERATURES

DOI: 10.1016/S0040-4039(00)86936-1

Source and publish data:

Tetrahedron Letters p. 743 - 746 (1982)

Update date:2022-08-05

Topics:

Authors:

Kaloustian, Moses K.

Khouri, Liliane

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Article abstract of DOI:10.1016/S0040-4039(00)86936-1

The sulfhydrolyses of thioimidate salts 2a-2d, in the presence of anh.NaSH in dry 2-butanone at -82 deg C, proceed by the preferential cleavage of the C-N bond rather than C-S bond.

Full text of DOI:10.1016/S0040-4039(00)86936-1

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