Glycol Ester Formation in the Reformatsky Reaction

DOI: 10.1021/jo00139a010

Source and publish data:

Journal of Organic Chemistry p. 3440 - 3442 (1982)

Update date:2022-08-02

Topics:

Authors:

Plattner, Jacob J.

Gawronska, Eva

Rinehart, Kenneth L.

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Article abstract of DOI:10.1021/jo00139a010

A previously unrecognized side reaction in the Reformatsky reaction has been identified in the reaction of heptanal with ethyl bromoacetate.The products are derived from the two isomeric heptanoates of the glycol 2-pentyl-3-hydroxynonanol, formed from 3 mol of heptanal under the presumed catalysis of the bromo zinc enolate.

Full text of DOI:10.1021/jo00139a010

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