SILICON-DIRECTED SELECTIVE GAMMA SUBSTITUTION OF AN Α,Β-UNSATURATED ESTER

DOI: 10.1016/S0040-4039(00)86931-2

Source and publish data:

Tetrahedron Letters p. 723 - 726 (1982)

Update date:2022-08-04

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Authors:

Albaugh-Robertson, Pamela

Katzenellenbogen, John A.

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Article abstract of DOI:10.1016/S0040-4039(00)86931-2

Ethyl 3-methyl-2-trimethylsilyl-3-butenoate (3) undergoes reaction selectively at carbon 4, upon treatment with a Lewis acid and carbonyl compounds, acetals, ketals, acid chlorides, and chloromethyl phenyl sulfide.This overall conversion represents a high

Full text of DOI:10.1016/S0040-4039(00)86931-2

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