A CONVERSION OF HUMULENE TO HIRSUTENE

DOI: 10.1246/cl.1982.855

Source and publish data:

Chemistry Letters p. 855 - 858 (1982)

Update date:2022-08-04

Topics:

Authors:

Misumi, Shunjiro

Matsushima, Hiroshi

Shirahama, Haruhisa

Matsumoto, Takeshi

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Article abstract of DOI:10.1246/cl.1982.855

Humulene has been transformed into 1,4,4-trimethyltricyclo-<6.2.1.0^2,6>undecan-11-one, a key intermediate for the synthesis of hirsutene, through a process which simulates the biosynthetic pathway assumed for the latter sesquiterpene.

Full text of DOI:10.1246/cl.1982.855

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