Tetrahedron Letters p. 1265 - 1268 (1983)
Update date:2022-08-04
Topics:
Oae, Shigeru
Asada, Kaoru
Yoshimura, Toshiaki
In the oxidation of the title compounds, 5-ethyl-4a-hydroperoxy-3-methyl-lumiflavin (4a-FlEt-OOH), was found to be an electrophilic oxidant similar to m-chloroperoxybenzoic acid.However, the stereoselectivity of the oxidation of cyclic sulfides to the corresponding sulfoxides by 4a-FlEt-OOH was less pronounced than that of the oxygenation with flavin-containing monooxygenase.
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Doi:10.1021/jm00159a012
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(2005)
