THE MECHANISTIC MODE OF OXIDATION OF SUBSTITUTED N,N-DIMETHYLANILINES, THIOANISOLES, AND METHYL PHENYL SULFOXIDES BY 5-ETHYL-4a-HYDROPEROXY-3-METHYL-LUMIFLAVIN (4a-FlEt-OOH)

DOI: 10.1016/S0040-4039(00)81631-7

Source and publish data:

Tetrahedron Letters p. 1265 - 1268 (1983)

Update date:2022-08-04

Topics:

Authors:

Oae, Shigeru

Asada, Kaoru

Yoshimura, Toshiaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)81631-7

In the oxidation of the title compounds, 5-ethyl-4a-hydroperoxy-3-methyl-lumiflavin (4a-FlEt-OOH), was found to be an electrophilic oxidant similar to m-chloroperoxybenzoic acid.However, the stereoselectivity of the oxidation of cyclic sulfides to the corresponding sulfoxides by 4a-FlEt-OOH was less pronounced than that of the oxygenation with flavin-containing monooxygenase.

Full text of DOI:10.1016/S0040-4039(00)81631-7

Products guided by the article

Product name:m-methyl-N,N-dimethylaniline-N-oxide

Cas No:825-80-9

R&D Labs maybe for 825-80-9

ANGCHEN BRIGHTCHEM CO., LTD

website:http://www.angchenchem.com

Contact:+86-510-88302099 82327577

Address:Rm. 404/405, Floor 4th, No. 983 FengXiang Road, Wuxi, China
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
QINGDAO NEW FLOURISH INTERNATIOANAL TRADE CO., LTD.

Contact:+86 532 80861829

Address:No. 1, Yinchuan East Road, 266061, Qingdao, China
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China

Relevant to this article

Selective thromboxane synthetase inhibitors. 3. 1H-Imidazol-1-yl-substituted benzo[b]furan-, benzo[b]thiophene-, and indole-2- and -3-carboxylic acids

Doi:10.1021/jm00159a012
(1986)
Spectroscopic, crystallographic and computational studies of the formation and isomerization of cyclic acetals and ketals of pentonolactones

Doi:10.1016/S0957-4166(00)80400-0
(1994)
New Modes of Bonding in Some Platinum Derivatives of B18H22: X-Ray Crystal Structures of <(Pt2B18H16)(PMe2Ph)4> and of Three Structural Isomers of <(PtB18H20)(PMe2Ph)2>

Doi:10.1039/c39820000080
(1982)
Investigating direct routes to an advanced intermediate for the synthesis of C-20 diterpene alkaloids

Doi:10.1016/j.tet.2005.02.014
(2005)
Identification and synthesis of [1,2,4]triazolo[3,4-a]phthalazine derivatives as high-affinity ligands to the α₂δ -1 subunit of voltage gated calcium channel

Doi:10.1016/j.bmcl.2004.03.008
(2004)
Synthesis of a caryophyllene isoprenologue, a potential diterpene natural product

Doi:10.1016/j.tet.2005.02.018
(2005)

Article Doi