VINYL-COPPER DERIVATIVES 15 : AN EFFICIENT SYNTHESIS OF POLYSUBSTITUTED CONJUGATED DIENES

DOI: 10.1016/S0040-4039(00)87166-X

Source and publish data:

Tetrahedron Letters p. 1589 - 1592 (1982)

Update date:2022-08-04

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Authors:

Jabri, N.

Alexakis, A

Normat, J. F.

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Article abstract of DOI:10.1016/S0040-4039(00)87166-X

Magnesium vinyl-copper derivatives, obtained by carbocupration of terminal alkynes, couple with 1-halo-1-alkenes, in the presence of Pd(PPh3)4 catalyst, to afford polysubstituted conjugated dienes in high yield and excellent stereoisomeric purity.

Full text of DOI:10.1016/S0040-4039(00)87166-X

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