
Tetrahedron Letters p. 1589 - 1592 (1982)
Update date:2022-08-04
Topics:
Jabri, N.
Alexakis, A
Normat, J. F.
Magnesium vinyl-copper derivatives, obtained by carbocupration of terminal alkynes, couple with 1-halo-1-alkenes, in the presence of Pd(PPh3)4 catalyst, to afford polysubstituted conjugated dienes in high yield and excellent stereoisomeric purity.
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