N-H Activation by O2 via O2.- in FeI(η5-C5H5)(η6-C6Me5NH2) and Subsequent Formation of an Amino-acid Zwitterion by Mild Reaction with CO2

DOI: 10.1039/c39820000416

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 416 - 417 (1982)

Update date:2022-08-04

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Authors:

Michaud, Pascal

Astruc, Didier

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Article abstract of DOI:10.1039/c39820000416

The thermally unstable complex Fe^I(cp)(C6Me5NH2), (cp = η⁵-C5H5) reacts with 1/4 mol of O2 at -10 deg C in toluene to give Fe^II(cp)(η⁵-C6Me5NH), the N-H being activated by O2, consistent with an electron transfe

Full text of DOI:10.1039/c39820000416

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