N-H Activation by O2 via O2.- in FeI(η5-C5H5)(η6-C6Me5NH2) and Subsequent Formation of an Amino-acid Zwitterion by Mild Reaction with CO2

DOI: 10.1039/c39820000416

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 416 - 417 (1982)

Update date:2022-08-04

Topics:

Authors:

Michaud, Pascal

Astruc, Didier

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820000416

The thermally unstable complex Fe^I(cp)(C6Me5NH2), (cp = η⁵-C5H5) reacts with 1/4 mol of O2 at -10 deg C in toluene to give Fe^II(cp)(η⁵-C6Me5NH), the N-H being activated by O2, consistent with an electron transfe

Full text of DOI:10.1039/c39820000416

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[η5-C5H5Fe-η5-C6(CH3)5NH2]+PF6-

Cas No:82879-24-1

R&D Labs maybe for 82879-24-1

TC CHEMICALS CO.,LTD

Contact:0550-7041128 0550-7090578

Address:Wangdian Street,Xinjie Town
Zhejiang Genebest Pharmaceutical Co.,Ltd.

Contact:0086-571-63532866

Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Jinan Hongfangde Pharmatech Co.LTD

Contact:0531-88870908

Address:F Bldg,750#,Shunhua Rd,New&High-tech Zone,Jinan,Shandong,China 250101
Tianjin Anda North Industrial & Business Co.Ltd.

Contact:86-22-24999306

Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
Hybio Pharmaceutica Co.,Ltd

website:http://www.hybio.com.cn

Contact:+86 755 26588093

Address:No.9 Linkong West Street, Hengdian Street, Huangpi District, Wuhan City, China.

Relevant to this article

Synthesis of CBI-PDE-I Dimer, the Benzannelated Analogue of CC-1065

Doi:10.1021/jo00049a035
(1992)
Doi:10.1002/hlca.6602801197
(1945)
Synthesis of Four Stereoisomeric Tetrose Derivatives from Propargyl Alcohol. One-carbon Homologation of Vinylsilanes via α,β-Epoxy Silanes

Doi:10.1021/jo00050a041
(1992)
Synthesis and NMR studies of chiral 4-oxazolidinones and rhodanines

Doi:10.1016/S0040-4020(01)88256-9
(1992)
A practical route to C-8 substituted fluoroquinolones

Doi:10.1016/S0040-4020(01)88273-9
(1992)
Gd(OTf)₃ catalyzed preparation of 2,3-unsaturated O-, S-, N-, and C-pyranosides from glycals by Ferrier Rearrangement

Doi:10.1016/j.tet.2015.11.002
(2016)

Article Doi