Synthesis of Four Stereoisomeric Tetrose Derivatives from Propargyl Alcohol. One-carbon Homologation of Vinylsilanes via α,β-Epoxy Silanes

DOI: 10.1021/jo00050a041

Source and publish data:

Journal of Organic Chemistry p. 6593 - 6598 (1992)

Update date:2022-08-04

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Authors:

Achmatowicz, Barbara

Raubo, Piotr

Wicho, Jerzy

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Article abstract of DOI:10.1021/jo00050a041

Silicon-mediated synthesis of stereomeric tetroses 1, 2, 3, and 4, from propargyl alcohol is described.An allylic alcohol bearing the trimethylsilyl group in the γ position, rac-9b, was subjected to the Sharpless kinetic resolution to give (2S)-9b and the

Full text of DOI:10.1021/jo00050a041

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