Journal of the American Chemical Society p. 3588 - 3594 (1983)
Update date:2022-08-04
Topics:
Chandraratna, Roshantha, A. S.
Bayerque, Ann L.
Okamura, William H.
The thermally induced <1,5>-sigmatropic rearrangement (69 deg C, 4 h) of the six-membered ring fused vinylallenol 5b, a process specific for preparing 11-cis-retinoids, afforded 24 (12percent) and the 12-s-cis-locked retinols 11-cis-7a (14percent), 11-cis
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