Stereoselectivity of Cycloaddition of N-(Cyanomethyl)- and N-(α-Cyanobenzyl)imines with Olefinic Dipolarophiles. Synthetic Equivalents of Nitrile Ylide 1,3-Dipoles

DOI: 10.1246/bcsj.59.1809

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1809 - 1824 (1986)

Update date:2022-08-05

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Authors:

Tsuge, Otohiko

Ueno, Kazunori

Kanemasa, Shuji

Yorozu, Kiyotaka

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Article abstract of DOI:10.1246/bcsj.59.1809

N-(Cyanomethyl)- and N-(α-cyanobenzyl)imines derived from a variety of aldehydes and ketones can tautomerize into N-protonated azomethine ylides which undergo cycloadditions with olefinic dipolarophiles.These cycloadditions are often accompanied by the el

Full text of DOI:10.1246/bcsj.59.1809

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