Synthesis p. 603 - 607 (1989)
Update date:2022-08-02
Topics:
Geraghty, Niall W. A.
Morris, Noreen M.
A range of 2-alkyl-2-cyclopenten-1-ones including the prostaglandin precursor 2-(6-methoxycarbonylhexyl)-2-cyclopenten-1-one and the jasmonoid precursor 2-<(Z)-2-pentenyl>-2-cyclopenten-1-one, have been prepared by a short synthetic route which begins with 6-methyl-5-hepten-2-one and generates the key 1,4-ketoaldehyde intermediates by a kinetic alkylation-ozonolysis procedure.
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Doi:10.1023/A:1015536927055
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(1984)Doi:10.1002/adsc.201300845
(2014)Doi:10.1016/0040-4039(80)80217-6
(1980)Doi:10.1021/jo00146a037
(1982)Doi:10.1021/ja01613a065
(1955)
