Canadian Journal of Chemistry p. 2797 - 2803 (1982)
Update date:2022-08-05
Topics:
Armand, Joseph
Boulares, Line
Bellec, Christian
Pinson, Jean
The electrochemical reduction of quinoxalino<2,3-b>quinoxaline gives fluoflavine (2) the structure of which is discussed.The electrochemical reduction of fluoflavine in acidic medium leads to a hexahydroquinolino<2,3-b>quinoxaline.A reduction mechanism is proposed based on cyclic voltammetry results and preparative electrolysis.The results obtained in the case of quinoxalino<2,3-b>quinoxaline are used to rationalize the results obtained in the case of pyrazino<2,3-b>pyrazines and pyrazino<2,3-b>quinoxalines.
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Doi:10.1055/s-1982-29958
(1982)Doi:10.1039/c3ra46759g
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(1965)Doi:10.1021/ja00341a086
(1983)Doi:10.1016/S0040-4020(01)93332-0
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