A HIGHLY STEREOSELECTIVE SYNTHESIS OF (E)-1- SUBSTITUTED-1,3-DIENES.

DOI: 10.1016/S0040-4039(00)87591-7

Source and publish data:

Tetrahedron Letters p. 3277 - 3280 (1982)

Update date:2022-08-05

Topics: Protecting groups Starting Material Purification and characterization Cross-Coupling Reactions Chiral Catalysts Elimination Reactions Chiral Auxiliaries

Authors:

Bloch, R.

Abecassis, J.

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Article abstract of DOI:10.1016/S0040-4039(00)87591-7

(E)-1-substituted-1,3-dienes are obtained with high selectivity by the thermal extrusion of SO₂ from 2-substituted-2,5-dihidrothiophene-1,1-dioxides generated by a retro Diels-Alder reaction.An application to the synthesis of (E)-9,11-dodecadien-1-yl acetate, a sex pheromone of the red-bollworm moth is described.

Full text of DOI:10.1016/S0040-4039(00)87591-7

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