Chemistry Letters p. 1291 - 1294 (1982)
Update date:2022-08-04
Topics:
Mukaiyama, Teruaki
Kato, Jun-ichi
Yamaguchi, Masahiko
Activated metallic tin, prepared from stannous chloride and metallic potassium, reacts readily with α-dicarbonyl compounds to form tin(II) enediolates, which in turn react with aldehydes under a mild reaction condition to give α,β-dihydroxy ketones in good yields.The reaction proceeds stereoselectively in the presence of hexafluorobenzene.
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Doi:10.1016/S0040-4039(00)87751-5
(1982)Doi:10.1016/S0022-328X(98)00752-9
(1998)Doi:10.1021/ml400377p
(2013)Doi:10.1021/jm00358a020
(1983)Doi:10.1021/ja00343a037
(1983)Doi:10.1016/S0040-4039(00)88648-7
(1982)
