Journal of the American Chemical Society p. 1325 - 1329 (1985)
Update date:2022-07-30
Topics:
Whitlock, Barabara J.
Whitlock, Howard W.
A series of ω-phenylalkyl esters of cyclophane 2 were synthesized.Cyclophane 2 has a cavity ca. 4.5 Angstroem by 6 Angstroem through which the phenylalkyl groups may pass.The activation energy for passage of the phenylalkyl groups through the cyclophane's cavity varies with structure in a manner which suggests dominant importance of alkyl group flexibility.These conclusions are supported by molecular mechanics calculations.
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