Bornanesultam-directed asymmetric synthesis of crystalline, enantiomerically pure syn aldols

DOI: 10.1021/ja00163a045

Source and publish data:

Journal of the American Chemical Society p. 2767 - 2772 (1990)

Update date:2022-08-05

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Authors:

Oppolzer, Wolfgang

Blagg, Julian

Rodriguez, Inès

Walther, Eric

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Article abstract of DOI:10.1021/ja00163a045

N-acylsultams 2 furnish, via aldolization of their enolates 16 with aldehydes, diastereomerically pure, crystalline syn aldols. The absolute configuration of the product is controlled by the choice of the enolate counterion: 16, M = B → 3; 16, M = Li or S

Full text of DOI:10.1021/ja00163a045

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Product name:1-Pentanol, 3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-methyl-, (2S,3S)-

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