Journal of Organometallic Chemistry p. 223 - 230 (1982)
Update date:2022-08-03
Topics:
Kolobova, N. E.
Ivanov, L. L.
Zhvanko, O. S.
Chechulina, I. N.
Batsanov, A. S.
Struchkov, Yu. T.
Reaction of Cp(CO)2Mn(η2-HC<*>CCO2Me) (I) with PPh3 or (Ph2PCH2-)2 gives rise to ?-?-rearrangement of the methylpropiolate ligand in I, yielding the phosphonium ylide complexes Cp(CO)2Mn-C(CO2Me)=CHP+Ph2R, where R = Ph or
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