REACTION OF (η-C5H5)(CO)2Mn(η2-HCCCO2Me) WITH PHOSPHINES. CRYSTAL AND MOLECULAR STRUCTURE OF (η-C5H5)(CO)2Mn--C(CO2Me)=CHP+Ph3

DOI: 10.1016/S0022-328X(00)84805-6

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Journal of Organometallic Chemistry p. 223 - 230 (1982)

Update date:2022-08-03

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Authors:

Kolobova, N. E.

Ivanov, L. L.

Zhvanko, O. S.

Chechulina, I. N.

Batsanov, A. S.

Struchkov, Yu. T.

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Article abstract of DOI:10.1016/S0022-328X(00)84805-6

Reaction of Cp(CO)2Mn(η²-HC<*>CCO2Me) (I) with PPh3 or (Ph2PCH2-)2 gives rise to ?-?-rearrangement of the methylpropiolate ligand in I, yielding the phosphonium ylide complexes Cp(CO)2Mn^-C(CO2Me)=CHP⁺Ph2R, where R = Ph or

Full text of DOI:10.1016/S0022-328X(00)84805-6

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