Solvolysis of 1-Aryl-2,2,2-trifluoroethyl Sulfonates. Kinetic and Stereochemical Effects in the Generation of Highly Electron-Deficient Carbocations

DOI: 10.1021/ja00346a039

Source and publish data:

Journal of the American Chemical Society p. 2343 - 2350 (1983)

Update date:2022-08-03

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Authors:

Allen, Annette D.

Ambidge, I. Christopher

Che, Claudius

Micheal, Hany

Muir, Ronald J.

Tidwell, Thomas T.

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Article abstract of DOI:10.1021/ja00346a039

Solvolysis rates of sulfonates XC6H4CH(O3SR)CF3 (R = p-Tol or CF3) correlate with ?⁺(X) with values of ρ⁺ between -6.7 and -11.9 depending upon solvent.For the tosylates the rates depend on the solvent parameter Y_OTs with

Full text of DOI:10.1021/ja00346a039

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