Solvolysis of 1-Aryl-2,2,2-trifluoroethyl Sulfonates. Kinetic and Stereochemical Effects in the Generation of Highly Electron-Deficient Carbocations

DOI: 10.1021/ja00346a039

Source and publish data:

Journal of the American Chemical Society p. 2343 - 2350 (1983)

Update date:2022-08-03

Topics:

Authors:

Allen, Annette D.

Ambidge, I. Christopher

Che, Claudius

Micheal, Hany

Muir, Ronald J.

Tidwell, Thomas T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00346a039

Solvolysis rates of sulfonates XC6H4CH(O3SR)CF3 (R = p-Tol or CF3) correlate with ?⁺(X) with values of ρ⁺ between -6.7 and -11.9 depending upon solvent.For the tosylates the rates depend on the solvent parameter Y_OTs with

Full text of DOI:10.1021/ja00346a039

Products guided by the article

Product name:Trifluoro-acetic acid 2,2,2-trifluoro-1-phenyl-ethyl ester

Cas No:84877-50-9

R&D Labs maybe for 84877-50-9

Xi'an Galaxy Chemicals CO., Ltd

Contact:86-29-89380370

Address:No.8, Gaoxin three road, Xi'an city.
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
Shandong Xinhua Pharmaceutical Co.,Ltd

website:http://www.xhzy.com

Contact:+86-533-2196801

Address:1 lutai road,zhangdian dis,Zibo City

Relevant to this article

Synthesis of macrocycles via cobalt-mediated [2 + 2 + 2] cycloadditions

Doi:10.1021/ja045001w
(2005)
Partial synthesis of C-ring derivatives from oleanolic and maslinic acids. Formation of several triene systems by chemical and photochemical isomerization processes

Doi:10.1016/j.tet.2003.12.023
(2004)
Enantio- and diastereoselective additions to aldehydes using the bifunctional reagent 2-(chloromethyl)-3-(tributylstannyl)propene: Application to a synthesis of the C₁₆-C₂₇ segment of bryostatin 1

Doi:10.1021/jo048308m
(2005)
Synthesis of poly(diphenylacetylene) membranes by desilylation of various precursor polymers and their properties

Doi:10.1021/ma047632g
(2005)
A short synthesis of morachalcone A

Doi:10.1016/j.tetlet.2005.01.174
(2005)
Condensation of pyrazol-5-ones unsubstituted in the position 1 with β-keto esters. Synthesis of pyrano[2,3-c]pyrazol-6-ones

Doi:10.1007/s10593-005-0159-7
(2005)

Article Doi