1496
M.G. Humphrey et al. / Journal of Organometallic Chemistry 690 (2005) 1487–1497
[9] C. Graiff, G. Predieri, A. Tiripicchio, Eur. J. Inorg. Chem. (2003)
1659, and references therein.
per pulse used in the measurements was generally in the
range of a few lJ/pulse and the repetition rate was set at
30 Hz. The power limiting curves were obtained by the
Z-scan technique. Open-aperture and closed-aperture
Z-scans were recorded simultaneously using a beam
splitter. The transmission vs. Z data were converted into
transmittance-fluence plots assuming Gaussian charac-
ter of the beam with the beam Rayleigh length zR
derived by numerical fitting of the closed-aperture
Z-scans. For most measurements in this series
zR = 1.35 mm.
[10] D. Belletti, D. Cauzzi, C. Graiff, A. Minarelli, R. Pattacini, G.
Predieri, A. Tiripicchio, J. Chem. Soc., Dalton Trans. (2002) 3160.
[11] C.H. Wei, L.F. Dahl, Inorg. Chem. 4 (1965) 493.
[12] K. Hashizume, Y. Mizobe, M. Hidai, Organometallics 15 (1996)
3303.
[13] B.F.G. Johnson, T.M. Layer, J. Lewis, A. Martin, P.R. Raithby,
J. Organomet. Chem. 429 (1992) C41.
[14] H. Brynner, J. Wachter, R. Wanninger, M. Zabel, J. Organomet.
Chem. 603 (2000) 125.
[15] P. Baistrocchi, D. Cauzzo, M. Lanfranchi, G. Predieri, A.
Tiripicchio, M. Tiripicchio-Camellini, Inorg. Chim. Acta 235
(1995) 173.
[16] P. Baistrocchi, M. Careri, D. Cauzzi, C. Graiff, M. Lanfranchi,
P. Manini, G. Predieri, A. Tiripicchio, Inorg. Chim. Acta 252
(1996) 367.
Acknowledgments
[17] R.D. Adams, J.E. Babin, M. Tasi, Organometallics 7 (1988)
219.
We thank the Australian Research Council for fund-
ing of this work. We also thank Johnson-Matthey for
the generous loan of RuCl3. V.-A.T is an ARC Austra-
lian Postdoctoral Research Fellow and M.G.H. is an
ARC Australian Professorial Fellow. We also thank
the Australian Partnership for Advanced Computing
(APAC) for time on the supercomputer.
[18] G. Hogarth, N.J. Taylor, A.J. Carty, A. Meyer, J. Chem. Soc.,
Chem. Commun. (1988) 834.
[19] M. Sheikh-bahae, A.A. Said, T. Wei, D.J. Hagan, E.W.V.
Stryland, IEEE J. Quantum Electron. 26 (1990) 760–769.
[20] I.R. Whittall, A.M. McDonagh, M.G. Humphrey, M. Samoc,
Adv. Organomet. Chem. 43 (1999) 349.
[21] R.L. Sutherland, Handbook of Nonlinear Optics, Marcel Dekker,
New York, 1996.
[22] M.I. Bruce, C.M. Jensen, N.L. Jones, Inorg. Synth. 28 (1990) 216.
[23] H.R. Hayes, D.J. Peterson, Organic Phosphorus Compounds,
Wiley–Interscience, New York, 1972, p. 341.
Appendix A. Supplementary data
[24] G.M. Kosolappoff, Organophosphorus Compounds, Wiley, New
York, 1950, p. 98.
Crystallographic data for the structural analysis has
been deposited with the Cambridge Crystallographic
Data Centre, CCDC no. 255342–255344 for compounds
1a, 3a, 3b. Copies of this information may be obtained
free of charge from The Director, CCDC, 12 Union
Road, Cambridge, CB2 1EZ, UK [fax. (int code):
+44(1223)336-033] or email: deposit@ccdc.cam.ac.uk
coordinates for all optimised structures described in this
article are available as supporting information. Supple-
mentary data associated with this article can be found,
[25] S.R. Hall, D.J. du Boulay, R. Olthof-Hazekamp (Eds.), The Xtal
3.7 System, University of Western Australia, Australia, 2000.
[26] A.C.T. North, D.C. Philips, F.S. Mathew, Acta Crystallogr., Sect
A 24 (1968) 351.
[27] L.J. Farrugia, J. Appl. Crystallogr. 32 (1999) 837.
[28] J.J. Barbour, J. Supramol. Chem. 1 (2001) 189.
[29] G.M. Sheldrick, SHELX97, Programs for Crystal Structure Anal-
ysis, University of Go¨ttingen, Go¨ttingen, 1997.
[30] A.D. Becke, J. Chem. Phys. 98 (1993) 5648.
[31] P.J. Stephens, J.F. Devlin, C.F. Chabalowski, M.J. Frisch, J.
Phys. Chem. 98 (1994) 11623.
[32] R.H. Hertwig, W. Koch, Chem. Phys. Lett. 268 (1997) 345.
[33] P.J. Hay, W.R. Wadt, J. Chem. Phys. 82 (1985) 299.
[34] R. Ditchfield, W.J. Hehre, J.A. Pople, J. Chem. Phys. 5 (1971)
724.
in
the
online
version
at
[35] W.J. Hehre, R. Ditchfield, J.A. Pople, J. Chem. Phys. 56 (1972)
2257.
References
[36] P.C. Hariharan, J.A. Pople, Mol. Phys. 27 (1974) 209.
[37] M.S. Gordon, Chem. Phys. Lett. 76 (1980) 163.
[38] P.C. Hariharan, J.A. Pople, Theo. Chim. Acta 28 (1973) 213.
[39] J.P. Blaudeau, M.P. McGrath, L.A. Curtiss, L. Radom, J. Chem.
Phys 107 (1997) 5016.
[1] I.G. Dance, in: A. Williams, C. Floriani, A. Merbach (Eds.),
Perspectives in Coordination Chemistry, VCH, Basel, 1992.
[2] M. Feliz, J.M. Garriga, R. Llusar, S. Uriel, M.G. Humphrey,
N.T. Lucas, M. Samoc, B. Luther-Davies, Inorg. Chem. 40
(2001) 6132.
[40] M.M. Francl, W.J. Pietro, W.J. Hehre, J.S. Binkley, D.J. DeFrees,
J.A. Pople, M.S. Gordon, J. Chem. Phys. 77 (1982) 3654.
[41] R.C. Binning Jr., L.A. Curtiss, J. Comp. Chem. 11 (1990) 1206.
[42] V.A. Rassolov, J.A. Pople, M.A. Ratner, T.L. Windus, J. Chem.
Phys. 109 (1998) 1223.
[3] S. Shi, W. Ji, J.P. Lang, X.Q. Xin, J. Phys. Chem. 98 (1994) 3570.
[4] W. Ji, S. Shi, S.H. Tang, J.P. Lang, X.Q. Xin, J. Phys. Chem. 99
(1995) 17297.
[5] Q.-F. Zhang, Y.-N. Xiong, T.-S. Lai, W. Ji, X.-Q. Xin, J. Phys.
Chem. B 104 (2000) 3446.
[43] V.A. Rassolov, M.A. Tatner, J.A. Pople, P.C. Redfern, L.A.
Curtiss, J. Comp. Chem. 22 (2001) 976.
[6] D. Cauzzim, C. Graiff, M. Lanfranchi, G. Predieri, A. Tiripicchio,
J. Organomet. Chem. 536–537 (1997) 497.
[44] M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A.
Robb, J.R. Cheeseman, J.A. Montgomery Jr., T. Vreven, K.N.
Kudin, J.C. Burant, J.M. Millam, S.S. Iyengar, J. Tomasi, V.
Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A.
Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R.
Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honsa, O.
[7] P. Braunstein, C. Graiff, C. Massera, G. Predieri, J. Rose´, A.
Tiripicchio, Inorg. Chem. 41 (2002) 1372.
[8] D. Cauzzi, C. Graiff, M. Lanfranchi, G. Predieri, A. Tiripicchio,
J. Chem. Soc., Dalton Trans. (1995) 2321.